Rate equation and order of a reaction.

  1. (a) Define the following terms

  1. Reaction rate.

  2. Order of a reaction.

  3. Rate equation.

  4. Overall order of a reaction.

(b) The data below were obtained for the following homogenous reaction

2NO(g) + 2H2(g) 2H2O(g) + N2(g)

NO(mol)

H2(mol)

Rate of formation of nitrogen(mol)

5.00 x 10-4

1.00 x 10-4

4.5 x 10-4

5.00 x 10-4

2.00 x 10-4

9.0 x 10-4

1.00 x 10-4

5.00 x 10-4

0.9 x 10-4

2.00 x 10-4

5.00 x 10-4

3.6 x 10-4

If the rate equation for the reaction is given by the expression

Rate = k

  1. Deduce the value of x.

  2. Deduce the value of y.

  3. Calculate the value of k and give its units.

(c) The data below was obtained for the reaction

A + B Products

Experiments

Initial concentration (moldm-3)

Rate (moldm-3s-1)

0.1

0.1

1.6 x 10-3

0.1

0.2

3.2 x 10-3

0.1

0.3

4.8 x 10-3

0.2

0.1

6.4 x 10-3

0.3

0.1

  1. Determine the order of the reaction with respect to B.

  2. Determine the value of w in the table.

  3. Write the rate equation of the reaction

  4. Calculate the value of rate constant and give its units.