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31 gt;8 ''-'Tunll 67%36210 pm I I I The (tgg)3 conguration here is simply a spherically symmetric (15 conguration, minus an (cg)2 hole conguration....

could you please explain how to derive S value of the spinning and symmetrical properties of the molecule?

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31 >8 fi’fi’é-‘Tunll 67%36210 pmI I I The (tgg)3 configuration here is simply a spherically symmetric (15 configuration,minus an (cg)2 hole configuration. To find the symmetry of the two holes, wetake Es ‘3 Eg : Alg + lAZgl + Es Since the two holes are in differentorbitals, their spatial component has to beantisymmetrised. Therefore, it is really theAgg state that we want here. As for the multiplicity, S = 3/2 gives28 -l- 1 : 4. Now that all the ground workhas been done, we can whizz through the remainingelectronic configurations — how exciting!It's a good idea to try working these outyourself before looking at the answer, tosee if you truly understand the conceptsabove. I'm also not going to comment onthe spin multiplicities any more — hopefullyyou can look at the diagram, calculate S,and work out 28 + 1 yourself. By using our site, you acknowledge that you have X read and understand our Cookie Policy, PrivacyPolicy, and our Terms of Service.
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