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For polymerization of styrene in tetrahydrofuran at 25C using sodium naphthalide as initiator, the rate constant for propagation is 550 dm 3 mol -1 s...
For polymerization of styrene in tetrahydrofuran at 25C using sodium naphthalide as initiator, the rate constant for propagation is 550 dm3mol-1s-1. If the initial mass concentration of styrene is 156 g dm-3 and that of sodium naphthalide is3.02 x 10-2 g dm-3, calculate the initial rate of polymeriztion and, for complete conversion of the styrene, the number-average molar mass of the polystyrene formed.Comment upon the expected value of the polydispersity index ( Mw/Mn )