Waiting for answer This question has not been answered yet. You can hire a professional tutor to get the answer.

QUESTION

How could IR spectroscopy be used to distinguish between benzene and cyclohexene?

Cyclohexene has strong aliphatic C-H stretching absorptions at 3000-2850 cm⁻¹. Benzene does not.

The characteristic IR absorptions of benzene are at

3100-3000 cm⁻¹: =C-H stretch ~1950 cm⁻¹: C=C stretch ~1800 cm⁻¹: C=C stretch 1500-1400 cm⁻¹: =C-H in-plane bending 900-650 cm⁻¹: =C-H out-of plane (oop) bending

The characteristic IR absorptions of cyclohexene are

3100-3000 cm⁻¹: =C-H stretch 3000-2850 cm⁻¹: C-H stretch ~1650 cm⁻¹: C=C stretch ~1450 cm⁻¹: CH₂ bend (scissoring) 1000-650 cm⁻¹: =C-H bend

The big difference is that cyclohexene has strong aliphatic C-H stretching peaks at 3000-2850 cm⁻¹.

Show more
LEARN MORE EFFECTIVELY AND GET BETTER GRADES!
Ask a Question