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QUESTION
If a mole of [Cr(CO)3(NO)2]o is treated with a mole ofPR3 (R is Hydrogen orFluorine) giving [Cr(PR3)(CO)2(NO)2]o via displacement of a moleCO from
If a mole of [Cr(CO)3(NO)2]o is treated with a mole ofPR3 (R is Hydrogen orFluorine) giving [Cr(PR3)(CO)2(NO)2]o via displacement of a moleCO from the "first coordination sphere", would thisreaction likely be more favorable if R = Hydrogen or if R =Fluorine? Why?
