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In what form are the vitamins riboflavin, thiamine, niacin, and pantothenic acid needed by the pyruvate dehydrogenase complex?

In what form are the vitamins riboflavin, thiamine, niacin, and pantothenic acid needed by the pyruvate dehydrogenase complex? In the oxidation of succinate to fumarate, what is the structural evidence that an oxidation reaction occurred? At which steps in the citric acid cycle do oxidation-reduction reactions occur?

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