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QUESTION

Phosphoric acid is a moderately weak triprotic acid that can lose 3 protons according to the following series of reactions:

Phosphoric acid is a moderately weak triprotic acid that can lose 3 protons according to the following series of reactions: 

????3????????4+????2????→????3????++????2????????4 −   Ka1 = 7.5 x 10-3

 ????2????????4 −+????2????→????3????++????????????4 2−   Ka2 = 6.2 x 10-8

 ????????????4 2−+????2????→????3????++????????4 3−     Ka3 = 2.2 x 10-13 

• Write down the equilibrium expressions for each of these reactions  

• Would a mixture of phosphoric acid (H3PO4) and sodium dihydrogen phosphate (NaH2PO4) be considered a buffer? Explain?  

• Would a mixture of sodium dihydrogen phosphate (NaH2PO4) and sodium hydrogen phosphate (Na2HPO4) also be considered a buffer? Explain?  

• What would be the pH of a solution that is 0.1 M in dihydrogen phosphate (????2????????4 −) and 0.1 M in hydrogen phosphate (????????????4 2−)?  

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