When HCl(aq) is titrated with NH3(aq), the pH at the equivalence point is (a) less than 7.0 (b) equal to 7.0 (c) greater than 7.0. ?

The answer is (b) ##"pH" < 7##

Hydrochloric acid, ##"HCl"##, a strong acid, will react with ammonia, ##"NH"_3##, a weak base, to form ammonium ions, ##"NH"_4^(+)## and chloride anions, ##"Cl"^(-)##.

At equivalent point, both the strong acid and the weak base have been consumed by this .

##"HCl"_text((aq]) + "NH"_text(3(aq]) -> "NH"_text(4(aq])^(+) + "Cl"_text((aq])^(-)##

The important thing to realize now is that the ammonium ion, which is the of ammonia, will actually react with the water molecules to reform some of the weak base and produce hydronium ions, ##"H"_3"O"^(+)##

##"NH"_text(4(aq])^(+) + "H"_2"O"_text((aql]) rightleftharpoons "NH"_text(3(aq]) + "H"_3"O"_text((aq])^(+)##

Since the concentration of hydronium ions increases as a result of this equilibrium reaction, the of the solution will decrease.

This means that the of a strong acid with a weak base will produce a solution of ##"pH" < 7## at equivalence point.

Similarly, titrating a weak acid with a strong base will produce a solution of ##"pH" > 7## at equivalence point, since the reaction produces the conjugate base of the acid, which then reacts with water to produce hydroxide anions, ##"OH"^(-)##.