Answered You can hire a professional tutor to get the answer.
Although the entropies of ideal gases calculated using statistical mechanics are in general consistent with the values measured by calorimetry....
Although the entropies of ideal gases calculated using statistical mechanics are in general consistent with the values measured by calorimetry. Sometimes discrepancy is observed. And when there is discrepancy, the experimental values are lower than the calculated values. What is the origin of the discrepancy?