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Consider an elementary, trimolecular reaction between non-linear molecules (NL), NL + NL + NL products According to transition state theory (TST),
Consider an elementary, trimolecular reaction between non-linear molecules (NL),
NL + NL + NL ® products
According to transition state theory (TST), the pre-exponential factor for the trimolecular reaction scales with temperature according to the relation, A ~ Tm. What is the value of m at moderate temperature when the transition state is a non-linear structure?