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1. Based on the experimental results (group A reactions), what conclusion can be drawn regarding the rate of reaction of the alkyl bromide vs. alkyl
1.
Based on the experimental results (group A reactions), what conclusion can be drawn
regarding the rate of reaction of the alkyl bromide vs. alkyl chloride? Is this conclusion in
accord with theory discussed in lecture regarding the SN2 mechanism? Explain (3 pts).
2.
Based on the experimental results(group C reactions), what conclusion can be drawn
regarding the rate of reaction of the tertiary alkyl bromide vs. tertiary alkyl chloride? Is
this conclusion in agreement with the conclusion drawn from the group A results? What
conclusion can be drawn regarding the rate of reaction of a tertiary alkyl halide vs.
secondary alkyl halide? Is the conclusion in agreement with theory discussed in lecture
regarding the SN1 mechanism? Explain (4 pts)?
3.
What are all the possible products of the reaction in group B? Which product would you
expect as the major one for this reaction? Which mechanistic pathway would be
predominant for the reaction? Explain (4 points)
4.
For the GC analysis of this reaction (group B), we do not have standard products,
however, comparing the starting material's retention time and new products appearing in
the GC can be done based on the boiling point of the compounds. Perform a literature
search to find the boiling points of the starting material ((3-bromopropyl)benzene and the
expected products. Which compound should have the highest retention time? Which
would have the lowest retention time? (5 points)
5.
Based on the GC results, what is the major product for the reaction? What was the effect
of temperature on the reaction outcome? Is this result in agreement with theory? (4 pts).
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